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Sulphonation ProductsCAS 121-03-9

PNTOSA

Para Nitro Toluene Ortho Sulphonic Acid

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Molecular Formula

C₇H₇NO₅S

Molecular Weight

217.20 g/mol

Appearance

White to off-white crystalline powder / wet cake

CAS Number

121-03-9

Synonyms:4-Nitrotoluene-2-sulphonic acidPNTOSAp-Nitrotoluene-o-sulphonic acid

Specifications

ParameterSpecification
AppearanceWhite to off-white crystalline powder / wet cake
Purity (by Nitrite value)Min. 82% (Technical) / Min. 99% (HPLC, Pure grade)
Free Acidity (as H₂SO₄)Max. 2.0%
Insoluble MatterMax. 0.2%
MoistureMax. 3.0%
SolubilityClear solution at 50% in water
Melting Point133–135°C
Molecular Weight217.20 g/mol
Molecular FormulaC₇H₇NO₅S

Quality & Testing Methods

HPLC (High Performance Liquid Chromatography)

Purity determination — C18 reverse phase column, mobile phase: acetonitrile:water with 0.1% H₃PO₄, UV detector at 254 nm

Nitrite Value Titration

Reduction with Zn/HCl followed by diazotisation with 0.1N NaNO₂, endpoint by starch-iodide paper

Karl Fischer Titration

Moisture determination per ASTM E203

Gravimetric Analysis

Insoluble matter — filtered through 0.45μm membrane, dried at 105°C

Solubility Test

Visual clarity at 50% concentration in water

Melting Point

Automated melting point apparatus

Applications

OBA manufacture (stilbene-based fluorescent whitening agents)
Reactive dye intermediates
Acid dye synthesis
Pharmaceutical intermediates
Agrochemical intermediates

Packaging

  • 25 kg HDPE bags
  • 50 kg HDPE bags
  • Jumbo bags (500/1000 kg)
  • Custom packaging available

Labelling: GHS/REACH compliant labelling. Export packaging available.

Incoterms: FOB Dahej/Nhava Sheva, CIF, CFR available.

Shipping

  • Export to EU, USA, South-East Asia, Middle East, Africa
  • GHS-compliant Safety Data Sheets (SDS) provided
  • UN dangerous goods classification as applicable
  • COA (Certificate of Analysis) with every shipment

Safety Information

Signal Word

Warning

Hazard Classification

Irritant (Skin/Eye)

GHS Pictograms

GHS07 – Exclamation Mark

Storage Conditions

Store in cool, dry, well-ventilated area. Keep away from moisture and strong alkalis.

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